Significantly improved dehydrogenation of LiBH4destabilized by TiF3
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چکیده
منابع مشابه
Significantly enhanced dehydrogenation properties of calcium borohydride combined with urea.
The interaction of [BH(x)]- and [NH(x)]-containing species gives rise to molecular hydrogen and the establishment of the B-N bond. Up to now, metal amides and ammonia are the commonly used [NH(x)] sources. Herein, urea, an organic carbonyl diamide, was used to react with Ca(BH4)2. A new type of complex hydride Ca(BH4)2·4CO(NH2)2 was synthesized with release of ca. 5.2 wt% hydrogen below 250 °C.
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ژورنال
عنوان ژورنال: Energy Environ. Sci.
سال: 2010
ISSN: 1754-5692,1754-5706
DOI: 10.1039/b915779d